![]() This led Carothers to foresee the possibility of making artificial fibers from linear-condensation superpolymers. In April 1930, his co-worker Julian Hill observed that a superpolyester could be mechanically drawn out from a melt or dry-spun from a solution into fibers or threads. This success was soon followed by the discovery of the “cold-drawing” phenomenon peculiar to these materials. Overcoming technical difficulties, his group was able to synthesize what he called “superpolymers,” polymers with molecular weights of ten thousand or more. If the products exhibited properties (such as elasticity and fibrousness) similar to natural polymers, then Staudinger’s claim that polymers were composed of macromolecules would be supported. He did not intend to produce a synthetic fiber when he started working at DuPont what he intended was simply to make molecules as large as he could in order to examine the properties of the products. By the time he joined DuPont in early 1928, Carothers had already developed his ideas into a coherent program for the synthesis of macromolecules by the use of established condensation reactions such as esterification. ![]() The unsettled German debate over the existence of macromolecules appealed to Carothers’s theoretical interest. Since the early 1920s, Staudinger had proposed the theory that polymers, such as rubber, cellulose, resins, and proteins, were made up of very large molecules, what he called “macromolecules.” His theory was severely criticized by many chemists, who claimed that polymers were the aggregates of relatively small molecules. Had it not been for the DuPont job offer, it is unlikely that the young Harvard instructor would have set out on a journey into the frontier of polymer research.Ĭarothers had been reading recent German articles on the structure of polymers by Hermann Staudinger and his opponents. Carothers chose polymers and polymerization as his new research subject because of the need for theoretical exploration as well as the vast commercial implications of polymers. In the spring of 1927, when DuPont approached Carothers to offer him a position in its newly established fundamental research program in Wilmington, Delaware, the company promised to leave the selection of research subject entirely to him. The synthetic-chemical approach and industrial orientation of Roger Adams at the University of Illinois also exerted a profound influence on Carothers’s style in chemistry and his career.īefore moving to the DuPont Company, Carothers had neither published nor performed any experiment in the field of polymers. ![]() While at Tarkio College in Missouri, Carothers decided on chemistry as his life’s work, largely at the encouragement of his chemistry teacher, Arthur M. Duncan’s popular books, The New Knowledge: A Popular Account of the New Physics and the New Chemistry in Their Relation to the New Theory of Matter (1905), an exposition of recent theories of matter, and The Chemistry of Commerce: A Simple Interpretation of Some New Chemistry in Its Relation to Modern Industry (1907), which stressed the importance of pure science for industry. When Carothers was a high school student in Des Moines, Iowa, his early interest in chemistry began with his reading of Robert K. Since the mid-1980s, a number of in-depth studies on Carothers, based on a large quantity of manuscripts, letters, and documents, have revealed some important aspects of his scientific career and work, such as his early encounter with chemistry, the origins of his polymer research, the process of his invention of nylon, and the industrial context in which Carothers worked on polymers.Įarly Years. For the original article on Carothers see DSB, vol. Philadelphia, Pennsylvania, 29 April 1937), chemistry, organic chemistry, polymer chemistry.
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The camera will count down to taking a picture, giving you time to get into frame. Timer: To shoot with the timer, trigger it by switching it down and hit the shutter. I hate camera blips and beeps, so I always turn this off. ![]() ![]() ![]() Basically, it changes the readout in the viewfinder to switch between using feet or meters as a measurement. Unit switch: This switch isn’t meant to be used often, so it’s recessed so it doesn’t accidentally get changed. On the back, from left to right, are the following controls: The Spectra System has a wealth of controls on the back that allow you to control everything from beeps to distance measurement units. The film is often still good, but you’ll need to do a battery transfer, and are still going to need a fresh pack of film to do so. Also, old packs of vintage Polaroid Spectra or Spectra Soft Tone film will likely have a dead battery. You can order Polaroid Originals Spectra film from Amazon and B&H, as well as directly from Polaroid Originals.įuji Instax film, and Polaroid Originals film for iType, SX-70, and 600 will not work with this camera. I’ll go over how to load the camera below, but before we get started, make sure you have a fresh pack of film in hand. The Polaroid Spectra System is powered by a small battery in the film cartridge itself, so it won’t even turn on until you load a new pack of film. Polaroid Originals film for Spectra is what you’ll need to operate the camera. In 2017, the Impossible Project renamed itself ‘Polaroid Originals,’ and continues making new film for vintage Polaroid cameras. Polaroid discontinued Spectra/1200/Image film way back in 2008, but a company called the Impossible Project rose up and started making new film for the camera. This film is interchangeably called Spectra, Type 1200, and Image. The Polaroid Spectra System uses a type of Polaroid film that’s slightly wider than the classic 600/SX-70 square frame. What Film Does the Polaroid Spectra System Use?īefore we get started, we need to make sure you have the film you’ll need for the camera. I’ll have a separate guide for the simpler cameras like the 1200i out soon. For this guide, we’re going to be looking at the cameras that have a full array of switches and autofocus. There are also variants of these cameras with different names that have much more limited controls. From here on, I will use ‘Spectra System’ to refer to both cameras. The main difference is the Spectra AF’s plastic body is a bit curvier, and the handle is also made of hard plastic. The guts of the camera, along with the controls, viewfinder, and lens, are practically identical. With lots of options, bright viewfinders, and autofocus, the Spectra System and Spectra AF cameras are solid workhorses.īoth the Polaroid Spectra System and Spectra AF are very similar cameras, despite having slightly different bodies, so I’m combining them into one guide. The Polaroid Spectra series of cameras are some of the best low-cost plastic rangefinders that Polaroid ever made. If you act fast, you might be able to snag some of the last film before it sells out completely. Update October 2019: Polaroid Originals has discontinued producing new film for Spectra, so this poor camera’s days are numbered. ![]() To help you stay trendy, we let you get high quality custom paintings for a very reasonable price. We work hard to provide our guests with a. A personalised portrait painting is a very popular gift idea today. Each year, the Florida Strawberry Festival hosts world-famous headline entertainment from all over the globe. 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In reef tanks, we create strong currents to mimic what corals and other reef animals would experience naturally. Sand sifting gobies and inverts should have smaller grain sand to ensure they can successfully sift and find food amongst the sand. Jawfish will benefit from medium-grade sand with larger crushed coral pieces and shells mixed in to create a burrow as they would naturally. For example, many Wrasse species should have small-medium grain sand beds to burrow into at night. For starters, there are some animals that prefer larger or smaller grain size sand so be sure your researching appropriately. The grain size or particle size is important for two reasons beyond the aesthetic. To learn more about using dry sand and how to rinse it, check out our video " Why Choose Dry Sand for Your Saltwater Aquarium Sand Bed?". ![]() Most dry sands should be rinsed prior to use in your display to help reduce the dust/sediment content. It is typically more affordable but requires a little extra work. Within the Caribsea live sand options, you have the "Oceans Direct" which is collected directly from the ocean and contains the natural biodiversity that comes along with it, and the "Araga-Alive" which is dry sand that is then combined with water that contains live beneficial bacteria before it is packaged.ĭry sand is exactly that, it is packaged dry and does not contain any living bacteria. It is packaged wet, has a low dust/sediment content and is designed to be poured directly into your display without any sort of rinsing or pretreatment required. Live sand is alive with beneficial bacteria that will help initiate or seed the nitrogen cycle in your display aquarium. After that, you should make your final choice based on grain size and color, both of which will affect the overall aesthetic and function of the sand in your reef tank.Ĭalculate how much sand you need using our Sand Bed Calculator. Having said that, you will first choose whether or not you want to use live or dry sand. Thanks.Since sand is a large part of your tank's aesthetic, we always like to advise you to choose sand that looks good to you. I want to make sure that I understand this theory. Before I ask my question can someone or everyone go over my understanding of this process that is part of a DSB. the denitrifying layer of the DSB has bacteria that converts the nitrite into nitrate which is released as dissolved nitrogen gas into the water column and into the air again. So the upper layer of the DSB has nitrifying bacteria which converts the ammonia, detritus and left over food into nitrite. Nitrate can be used by plant life as a nutrient or can be reduced to dinitrogen gas (N2) through denitrifying bacteria. Nitrifying bacteria quickly oxidize ammonia into first nitrite then nitrate. Bacterial activity quickly changes the urea and uric acid in ammonia. ![]() The first method is by Animals eating the plants and is excreted back into the environment as urea, uric acid or ammonia. These proteins eventually reenters the environment as ammonia, through 2 ways, I'll only talk about one. Through photosymthesis plants incorporate nitrogen into the proteins of there tissues. ![]() Nitrogen(building block of life) is introduced into seawater as nitrogen gas, certain bacteria and blue green algae convert nitrogen into nutrients for plants. This is what I understand about DSB and how it is helpful, please correct me if I am wrong I really don't mind. I will Probably will get a lot of replies on this one. Thanks everyone for your input really appreciate it. ![]() ![]() Most of Islegand is now the area around Westronbolt Gorge. ![]() It is said that the capital of a kingdom that once covered this land sleeps within the lake's silent depths. Additionally here's the description of the Perniya Cliffside path: They also mention however that the land is sacking and might just sink completely. I'll combine them because they are right next to each other and the reasoning is the same: They lie between two cities we can be sure of are located exactly: Loegres/Pendrago and Stonebury/Lastonbell.Ī few mentions of the Hyland kingdom having once been there are made at several points in time in Taliessin. A nice reference is also that in Zestiria this is the place where you fight the legendary Wyvvern Zaveid allowed to escape in Lothringen during Berseria.Īldina Plains = Meadow of Triumph and Danaan Highway = Pearloats Pasture The most telling is the location, the geographic relation to Lothringen and the striking resemblance between the the Fens of Nog and Plitzerback Wetlands. Reneed = unnamed remains in the south of Plitzerback Wetlands And they also mention the name Tintagel in Stonebury at a point. ![]() There are the Radishbells mentioned too in both town and to confirm this once and for all: The forest around Stonebury (mentioned by a few villagers at different times in the game) is called Volgran Forest - just like in Zestiria (and yes, I know, there's also Duvahl Forest close by, but they mention Volgran forest by name). There are several plans mentioned about building a bell tower in Stonebury. Reoccuring locations sources: maps of both games, mentionings throughout Berseriaįor one the size but most importantly the shrine church is definitely the same structure. Strongly impliedThis part is about parts in the game that are just a bit shy about spilling the beans but with just one more nudge the story is told I still decided to make it a different section though :3 This distinction seems to no longer be in play in Zestiria, because Edna for sure is a malak while Mikleo is a seraph. It's worth looking up that scene Eizen is so schocked he is physically the same as the Heavenly Sent Ones XD The malakhim have descended to live amongst humans while the seraphim remain in Elysia. XD).īut before that we get a few very important scenes which include the difference between malakhim and seraphim: their location. I'll add this because many of you may not have completed this dungeon - no one would blame you, omg -and only watched the bonus scene (hilarious. The difference between Malakhim and Seraphim source: EX dungeon: heavenly steps Personally, I rank the focus stat equal to the attack stat for melee fighters. So if you're having issues with the combat system, try upping the Focus stat with all your equipment to experience the difference ^^ Unnamed boots are your best friend for that. So in Berseria this stat is very important and they should have seriously put more effort into telling us all. Next to all the side effects that artes can have, the most important ones are the stun rate and status ailment infliction rate due to how the Soul system works in combat. Focus increases combo capability by increasing SG regeneration and upping the effect rates. The Focus statI list this here because I have not come across even one person who knew what this did until I told them.Īnd really, the infromation is sorta hidden so who can blame them.Īnyways, take it from the Red Chamomile description:Īn herb that increases Focus by 3, improving SG regeneration and arte effect rates. No need to worry about bloodstains with this.Įleanor (Normal Style): Eleanor's same hairstyle since she was a girl. Rokurou (Flame Normin suit): A fire normin body for Rokurou. Magilou (Swim wear): She's more embarrassed to be seen in something plain than something indecent. Undressing didn't used to make his heart race. Laphicet (Hot Spring Clothes): A Katz Towel to wrap up in. He might try doing the voice if no one is listening. Makes feel like she can breathe fire!Įizen (mieu head): A mieu head for Eizen. Velvet (mieu head): A mieu head for Velvet. There are a lot things and you should definitely go and read them all for your favorite characters ^^ I decided to list my most telling fashion description per character :3 The last part of the journal is reserved for continuity errors between Berseria and Zestiria that I came to realize.įashion items/costumes/hair stylesThe descriptions of these are so very telling. The lower you go down this journal, the more deducting is involved. I split it up into Literal, Strongly implied and Hypothesized. (okay admittedly, some are not as fun and more horribly sad, but you know the game, so.no surprise there)ĪLSO - SPOILER ALERT OF THE HIGHEST ORDER ![]() The apply command is happy to apply a stash to a modified working tree (or at least, to try to apply it). This is true even if you already have some changes. (This simplified version looks only at the "final work tree" changes, not the saved index changes that -index restores separately.) The command git stash apply, without -index, just tries to make those same changes in your working tree now. The stash will still be there ( apply keeps it around), so you can look at it more, or decide this was the wrong place to apply it and try again differently, or whatever.Īny time you have a stash, you can use git stash show -p to see a simplified version of what's in the stash. The apply operation looks at what the commit changed and tries to repeat it wherever you are now. The main thing to remember is that the "stash" is a commit, it's just a slightly "funny/weird" commit that's not "on a branch". Git stash apply # apply stashed changes see below about -index ![]() Git checkout -b temp # optional: create a new branch for "apply" Or maybe it goes more like this: git status # see if there's anything you need to commit Git checkout -b temp # create new temp branch to save stuff # uh oh, there is - let's put it on a new temp branch That way the "somewhere" that you are applying them, has nothing else in it, and you'll just be trying the stashed changes: git status # see if there's anything you need to commit This one is beyond the scope of this answer see this other StackOverflow answer instead.įor complicated cases, I recommend starting in a "clean" working tree first, by committing any changes you have now (on a new branch if you like). You're using git stash save -keep-index in order to test "what will be committed". So now you use git stash apply -index, and that sometimes fails with: Conflicts in index. You had one version in the stashed index/staging area and another (different) version in the working tree. (Extra-advanced) You've used git stash save -p, or carefully git add-ed and/or git rm-ed specific bits of your code before running git stash save. I personally prefer to transfer these changes to a new branch, because branches have names, and cleanup-attempt-in-December means a lot more to me than (The git stash command takes an optional save-message, and those can help, but somehow, all my stashes just wind up named WIP on branch.) Again, the one without a number is also you pile up a lot of stashes, it can get fairly messy (was the stash I wanted or was it Wait, I just pushed another, now they're 8 and 5?). Dropping a specific stash renumbers only the higher-numbered ones. You can apply and then drop a specific stash, too: git stash apply and so on. If you had, even more, the one that was becomes and so on. When you git stash drop, it drops the newest, and the one that was moves to the top of the stack. The newest is always the lowest-numbered. If you do that, you have two stashes, one just called stash-but you can also write one spelled Use git stash list (at any time) to see them all. You can in fact git stash save again, as git stash makes a "stack" of changes. Now you want to keep, or even move, these changes, and apply your stash too. Then you switched to another branch and started more changes, forgetting that you had the stashed ones. You started some changes and stashed them.Inspect the results carefully (with git diff) to see if you like them, and if you do, use git stash drop to drop the stash. This gets Git to merge in your earlier changes, using Git's rather powerful merge mechanism. Check out the other branch and use git stash apply. Run git stash save (or plain git stash, same thing). You just want to take the changes you have now and "move" them to another branch. You started with a clean branch, were working on some changes, and then realized you were doing them in the wrong branch.The above is for "way 1", the "easy way": There are at least three or four different "ways to use git stash", as it were. What if you're doing more-advanced or more-complicated stuff? It's all pretty minor one way or the other though, and for a newbie to Git, it should be about the same. If you apply, you get to choose when to drop. If pop is able to extract the stash, it will immediately also drop it, and if you subsequently realize that you wanted to extract it somewhere else (in a different branch), or with -index, or some such, that's not so easy. The difference is that apply leaves the stash around for easy re-try of the apply, or for looking at, etc. I always suggest using git stash apply rather than git stash pop. Then use git diff to see the result.Īfter you're all done with your changes-the apply looks good and you're sure you don't need the stash any more- then use git stash drop to get rid of it. Just check out the branch you want your changes on, and then git stash apply. The easy answer to the easy question is git stash apply |